small isc logo

Chuiko Institute of Surface Chemistry

National Academy of Sciences of Ukraine
(official site)

Laboratory of Oxide Nanocomposites

 bori

 

Head of Laboratory

Borysenko Mykola V.

PhD in Chemistry, Senior Researcher

 

Telephone: + 380 44 422-96-72

Fax: +380 44 424-35-67

E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

 

Laboratory staff is 7 co-workers including 6 PhDs. From 1986, the Laboratory researchers have published more than 300 scientific papers, obtained 20 patents for inventions, and 8 candidate dissertations were defended.

 

Directions of investigations

Chemical reactions of disperse silica with chlorides, oxochlorides, and acetylacetonates of transition and rear-earth metals; synthesis of oxide nanoparticles and layers of Zr, Ti, Cr, Ni, Co, Fe, Cu, Ce, Eu, Ho/Yb, Er/Yb and other metals on surfaces of silica matrices; phase and dimensional transformations of a deposited metal oxide phase on silica surface during the course of processes of synthesis, hydrolysis, and calcination; sol-gel method for producing doped silica glass and nanocomposites; spectral properties of glass and glass-ceramic systems doped with transition and rear-earth metals. X-ray diffraction studies of weakly crystalline metal oxides. Development of anticorrosive pigments and protective antimicrobial coatings resistant to biofouling based on highly dispersed modified silica, carbon materials and polymeric biocides.

 

Main results for the recent years

A method for the synthesis of preparative batches of nanocomposites of CuO/SiO2 and CeO2/SiO2 composition using metal acetylacetonate precursors has been developed. The method allows to obtain nanoparticles of monoclinic modification of CuO, tenorite with a crystallite size of ~ 80 nm and their content in CuO/SiO2 2.1–6.1 wt. %, as well as X-ray amorphous and crystalline CeO2 with a particle size of 3–25 nm. It was found that the threshold for determining the crystalline phase of CeO2 by X-ray diffraction is 12–15% and does not depend on the method of nanocomposite synthesis (molecular layering or impregnation). In the concentration range of 12–23% CeO2 and in the heat treatment of nanocomposites at 550°C, cerium dioxide nanoparticles of 3–4 nm are formed. An increase in temperature leads to sintering of silica and agglomeration of CeO2, while nanoparticles are enlarged to 16–25 nm.

A new variant of sol-gel synthesis of xerogels and quartz glass doped with nanoparticles of transition metal oxides is proposed, which involves the introduction of metal-containing highly dispersed silica as fillers and dopants in alkoxide-formed sols. Such materials can be used as high-temperature light transducers, light filters, catalysts, adsorbents, etc. The sol-gel doped glass has a high optical homogeneity and contains ~ 0.3 wt. % of OH groups. Alloying additives to quartz glass – nanoparticles ZrO2, CeO2, Fe2O3, Eu2O3, Cr2O3 and CuO lead to an increase in refractive index compared to pure quartz glass.

Plastic lubricants with high mechanical stability and heat resistance (Patent of Ukraine № 99227) and new anticorrosive pigments for the protection of metals that do not contain hexavalent chromium (US Patent Application US20070088111 A1, US20130071682 A1) have been developed using oxides modified with  silica metals.

 

Laboratory staff

Borysenko Mykola V., PhD, Head of Laboratory,

tel.: +38 (044) 4229672; e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

Cherniavska Tetiana V., PhD, Senior Researcher,

tel.: +38 (044) 4229672; +380 97 4460382, e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

Dyachenko Alla G., PhD, Senior Researcher,

tel.:+38 (044) 4229672; e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

Galaburda Mariya V., PhD, Senior Researcher,

tel.: +38 (044) 4229672; e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

GornikovYuri I., leading engineer,

tel.: +38 (044) 4249470; e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

Oranska Olena I., PhD, Senior Researcher,

tel.: +38 (044) 4249470; e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

Sulym Iryna Ya., PD, Senior Researcher,

tel.: +38 (044) 4229672; e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.

 

Recent publications

1. I.Ya. Sulym, P. Veteška, R. Klement, Z. Hajdúchová, J. Lokaj, A. Gatial, M.V. Borysenko, M. Janek, D.V. Gryn, M.S. Yakhnenko, A.P. Naumenko. Structural, optical and lumines cence features of Er3+/Yb3+ co-doped sol-gel silica glasses // Functional Materials. – 2021. – V. 28, N. 1. – P. 14–21.

2. O.S. Yakovenko, L.Yu. Matzui, L.L. Vovchenko, V.M. Bogatyrov, M.V. Galaburda, A.V. Bodnaruk, V.M. Kalita, O.A. Syvolozhskyi, V.V. Vilchinskyi. Electric properties of Ni-C and Co-C core–shell nanoparticles in polymer matrix // Molecular Crystals and Liquid Crystals – V. 718(1). – 2021/07/19 – P. 132–141.

3. M. Chodkowski, I.Ya. Sulym, K. Terpiłowski, D. Sternik. Surface properties of silica–MWCNTs/PDMS composite coatings deposited on plasma activated glass supports // Applied Sciences. – 2021. – V. 11. – 9256.

4. M. Nazarkovsky, B. Czech, A. Żmudka, V. Bogatyrov, O. Artiushenko, V. Zaitsev, T. Saint-Pierre, R. Rocha, J. Kai, Yu. Xing, W. Gonçalves, A. Veiga, M. Rocco, S. Safeer, M. Galaburda, V. Carozo, R. Aucélio, R. Caraballo-Vivas, O. Oranska, J. Dupont. Structural, optical and catalytic properties of ZnO-SiO2 colored powders with the visible light-driven activity // J. Photochem. Photobiol., A.– 2021/12/1. – V. 421. – P. 113532.

5. M. Galaburda, V. Bogatyrov, D. Sternik, O. Oranska, M. Borysenko, I. Škorvánek, E. Skware, A. Deryło-Marczewska, V. Gun’ko. Magneto-sensitive carbon-inorganic composites based on particleboard and plywood wastes // Chemistry journal of Moldova. – 2021. V. 16(1) – P. 68–78.

6. I. Sulym, M. Wiśniewska, L. Storozhuk, K. Terpilowski, D. Sternik, M. Borysenko, A. Derylo-Marczewska. Investigation of surface structure, electrokinetic and stability properties of highly dispersed Ho2O3–Yb2O3/SiO2 nanocomposites // Applied Nanoscience. – 2021/2/13 – P. 1–12.

7. А.G. Dyachenko, O.V. Ischenko, O.V. Goncharuk, M.V. Borysenko, O.V. Mischanchuk, V.M. Gun’ko, D. Sternik, V.V. Lisnyak. Preparation and characterization of Ni–Co/SiO2 nanocomposite catalysts for CO2 methanation // Applied Nanoscience. – 2021/1/28. – P. 1–11.

8. S. Rogalsky, J.-F. Bardeau, L. Lyoshina, O. Tarasyuk, O. Bulko, O. Dzhuzha, T. Cherniavska, V. Kremenitsky, L. Kobrina, S. Riabov. New promising antimicrobial material based on thermoplastic polyurethane modified with polymeric biocide polyhexamethylene guanidine hydrochloride // Materials Chemistry and Physics. – 2021/7/15. – V. 267. – 124682.

9. K. Kulyk, L. Azizova, J.M. Cunningham, L. Mikhalovska, M. Borysenko, S. Mikhalovsky. Nanosized copper (ii) oxide/silica for catalytic generation of nitric oxide from S-nitrosothiols // Journal of Materials Chemistry B – 2020. – V8, N19. – P. 4267-4277.

 

Новини

 

Звіт про діяльність Національної академії наук України у 2021 році 

 

Read more...

 

 На сайті SCImago Journal & Country Rank оновлено рейтинги періодичних видань

 

Read more...

 

 Інформація про платформу "Наука та бізнес"

 

Read more...

 

 Програма імені Фулбрайта, попри трагічні події російсько-української війни, підтверджує свою присутність в Україні, продовжує діяльність та приймає заявки від українських конкурсантів на здобуття стипендій для навчання, стажування та проведення досліджень у США!

До 30 червня 2022 року триває подання аплікаційного пакету документів на участь у конкурсі FULBRIGHT FOREIGN LANGUAGE TEACHING ASSISTANT (FLTA) Program на 2023-2024 академічний рік. 

 

Read more...

 

 Інформація про програми Товариства імені Макса Планка

 

Read more...

Conferences

 

Ukrainian conference with international participation 

"CHEMISTRY, PHYSICS AND TECHNOLOGY OF SURFACE"

 

and

Workshop

"MICROWAVES AND NANOPARTICLES FOR REAL-TIME DETECTION OF HUMAN PATHOGENS " 

(multinational research NATO SPS project G5798 «A novel nanoparticle based real-time sensor for B. anthracis and M. Tuberculosis»)

 

 

 

19-20 October, 2022, Kyiv

 

 

Read more...

Stop War in Ukraine

stop War in UKraine2

Спільне звернення НАН і МОН

Спільне звернення Міністерства освіти і науки України, Національної академії наук України, народних депутатів до міжнародної наукової спільноти

download-pdf-icon

Реєстр наукових фахових видань України

Покажчик друкованих праць